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The Introduction of Stainless Steel

Update: 2014-07-11 20:05:16  Clicks: 3555

Stainless steel From Wikipedia, the free encyclopedia
In metallurgy, stainless steel, also known as inox steel or inox from French "inoxydable", is a steel alloy with a minimum of 10.5% chromium content by mass.Stainless steel does not readily corrode, rust or stain with water as ordinary steel does, but despite the name it is not fully stain-proof, most notably under low-oxygen, high-salinity, or poor-circulation environments.There are different grades and surface finishes of stainless steel to suit the environment the alloy must endure. Stainless steel is used where both the properties of steel and resistance to corrosion are required.
Stainless steel differs from carbon steel by the amount of chromium present. Unprotected carbon steel rusts readily when exposed to air and moisture. This iron oxide film (the rust) is active and accelerates corrosion by forming more iron oxide, and due to the greater volume of the iron oxide this tends to flake and fall away. Stainless steels contain sufficient chromium to form a passive film of chromium oxide, which prevents further surface corrosion by blocking oxygen diffusion to the steel surface and blocks corrosion from spreading into the metal's internal structure, and due to the similar size of the steel and oxide ions they bond very strongly and remain attached to the surface.
Passivation only occurs if the proportion of chromium is high enough and oxygen is present.
  History 
A few corrosion-resistant iron artifacts survive from antiquity. A famous example is the Iron Pillar of Delhi, erected by order of Kumara Gupta I around AD 400.Unlike stainless steel, however, these artifacts owe their durability not to chromium but to their high phosphorus content, which, together with favorable local weather conditions, promotes the formation of a solid protective passivation layer of iron oxides and phosphates, rather than the non-protective cracked rust layer that develops on most ironwork.The corrosion resistance of iron-chromium alloys was first recognized in 1821 by French metallurgist Pierre Berthier, who noted their resistance against attack by some acids and suggested their use in cutlery. Metallurgists of the 19th century were unable to produce the combination of low carbon and high chromium found in most modern stainless steels, and the high-chromium alloys they could produce were too brittle to be practical.In the late 1890s Hans Goldschmidt of Germany developed an aluminothermic (thermite) process for producing carbon-free chromium. Between 1904 and 1911 several researchers, particularly Leon Guillet of France, prepared alloys that would today be considered stainless steel.Friedrich Krupp Germaniawerft built the 366-ton sailing yacht Germania featuring a chrome-nickel steel hull in Germany in 1908. In 1911, Philip Monnartz reported on the relationship between chromium content and corrosion resistance. On 17 October 1912, Krupp engineers Benno Strauss and Eduard Maurer patented austenitic stainless steel as Nirosta.
Similar developments were taking place contemporaneously in the United States, where Christian Dantsizen and Frederick Becket were industrializing ferritic stainless steel. In 1912, Elwood Haynes applied for a US patent on a martensitic stainless steel alloy, which was not granted until 1919.
Also in 1912, Harry Brearley of the Brown-Firth research laboratory in Sheffield, England, while seeking a corrosion-resistant alloy for gun barrels, discovered and subsequently industrialized a martensitic stainless steel alloy. The discovery was announced two years later in a January 1915 newspaper article in The New York Times. The metal was later marketed under the 'Staybrite' brand by Firth Vickers in England and was used for the new entrance canopy for the Savoy Hotel in London in 1929. Brearley applied for a US patent during 1915 only to find that Haynes had already registered a patent. Brearley and Haynes pooled their funding and with a group of investors formed the American Stainless Steel Corporation, with headquarters in Pittsburgh, Pennsylvania.
In the beginning stainless steel was sold in the US under different brand names like 'Allegheny metal' and 'Nirosta steel'. Even within the metallurgy industry the eventual name remained unsettled; in 1921 one trade journal was calling it "unstainable steel". In 1929, before the Great Depression hit, over 25,000 tons of stainless steel were manufactured and sold in the US.
  Properties 
Oxidation
High oxidation resistance in air at ambient temperature is normally achieved with additions of a minimum of 13% (by weight) chromium, and up to 26% is used for harsh environments.The chromium forms a passivation layer of chromium(III) oxide (Cr2O3) when exposed to oxygen. The layer is too thin to be visible, and the metal remains lustrous and smooth. The layer is impervious to water and air, protecting the metal beneath, and this layer quickly reforms when the surface is scratched. This phenomenon is called passivation and is seen in other metals, such as aluminium and titanium. Corrosion resistance can be adversely affected if the component is used in a non-oxygenated environment, a typical example being underwater keel bolts buried in timber.
When stainless steel parts such as nuts and bolts are forced together, the oxide layer can be scraped off, allowing the parts to weld together. When forcibly disassembled, the welded material may be torn and pitted, an effect known as galling. This destructive galling can be avoided by the use of dissimilar materials for the parts forced together, for example bronze and stainless steel, or even different types of stainless steels (martensitic against austenitic). However, two different alloys electrically connected in a humid environment may act as Voltaic pile and corrode faster. Nitronic alloys made by selective alloying with manganese and nitrogen may have a reduced tendency to gall. Additionally, threaded joints may be lubricated to prevent galling.
Acids
Stainless steel is generally highly resistant to attack from acids, but this quality depends on the kind and concentration of the acid, the surrounding temperature,and the type of steel. Type 304 is resistant to sulfuric acid at room temperature, even in high concentrations, but type 316 and 317 are only resistant at low concentrations. All types of stainless steel resist attack from phosphoric acid, 316 and 317 more so than 304; and Types 304L and 430 have been successfully used with nitric acid. Hydrochloric acid will damage any kind of stainless steel, and should be avoided.
Bases
The 300 series of stainless steel grades is unaffected by any of the weak bases such as ammonium hydroxide, even in high concentrations and at high temperatures. The same grades of stainless exposed to stronger bases such as sodium hydroxide at high concentrations and high temperatures will likely experience some etching and cracking, especially with solutions containing chlorides.
Organics
Types 316 and 317 are both useful for storing and handling acetic acid, especially in solutions where it is combined with formic acid and when aeration is not present (oxygen helps protect stainless steel under such conditions), though 317 provides the greatest level of resistance to corrosion. Type 304 is also commonly used with formic acid though it will tend to discolor the solution. All grades resist damage from aldehydes and amines, though in the latter case grade 316 is preferable to 304; cellulose acetate will damage 304 unless the temperature is kept low. Fats and fatty acids only affect grade 304 at temperatures above 150 °C(302 °F), and grade 316 above 260 °C (500 °F), while 317 is unaffected at all temperatures. Type 316L is required for processing of urea.
Electricity and magnetism
Similarly to steel, stainless steel is a relatively poor conductor of electricity, with a few percent of the electrical conductivity of copper.Ferritic and martensitic stainless steels are magnetic. Austenitic stainless steels are non-magnetic.
  Applications 
Stainless steel's resistance to corrosion and staining, low maintenance and familiar lustre make it an ideal material for many applications. There are over 150 grades of stainless steel, of which fifteen are most commonly used. The alloy is milled into coils, sheets, plates, bars, wire, and tubing to be used in cookware,cutlery, household hardware, surgical instruments, major appliances, industrial equipment (for example, in sugar refineries) and as an automotive and aerospace structural alloy and construction material in large buildings. Storage tanks and tankers used to transport orange juice and other food are often made of stainlesssteel, because of its corrosion resistance. This also influences its use in commercial kitchens and food processing plants, as it can be steam-cleaned and sterilized and does not need paint or other surface finishes.
Stainless steel is used for jewelry and watches with 316L being the type commonly used for such applications. It can be re-finished by any jeweler and will not oxidize or turn black.
Some firearms incorporate stainless steel components as an alternative to blued or parkerized steel. Some handgun models, such as the Smith & Wesson Model 60 and the Colt M1911 pistol, can be made entirely from stainless steel. This gives a high-luster finish similar in appearance to nickel plating. Unlike plating, the finish is not subject to flaking, peeling, wear-off from rubbing (as when repeatedly removed from a holster), or rust when scratched. Some automotive manufacturers use stainless steel as decorative highlights in their vehicles.
  Types of Stainless Steel 
There are different types of stainless steels: when nickel is added, for instance, the austenite structure of iron is stabilized. This crystal structure makes such steels virtually non-magnetic and less brittle at low temperatures. For greater hardness and strength, more carbon is added. With proper heat treatment, these steels are used for such products as razor blades, cutlery, and tools.
Significant quantities of manganese have been used in many stainless steel compositions. Manganese preserves an austenitic structure in the steel, similar to nickel, but at a lower cost.Stainless steels are also classified by their crystalline structure:
Austenitic, or 200 and 300 series, stainless steels have an austenitic crystalline structure, which is a face-centered cubic crystal structure. Austenite steels make up over 70% of total stainless steel production. They contain a maximum of 0.15% carbon, a minimum of 16% chromium and sufficient nickel and/or manganese to retain an austenitic structure at all temperatures from the cryogenic region to the melting point of the alloy.
200 Series—austenitic chromium-nickel-manganese alloys. Type 201 is hardenable through cold working; Type 202 is a general purpose stainless steel.Decreasing nickel content and increasing manganese results in weak corrosion resistance.
300 Series—The most widely used austenite steel is the 304, also known as 18/8 for its composition of 18% chromium and 8% nickel.[23] 304 may be referred to as A2 stainless (not to be confused with A2 grade steel, also named Tool steel, a steel). The second most common austenite steel is the 316 grade, also called marine grade stainless, used primarily for its increased resistance to corrosion. A typical composition of 18% chromium and 10% nickel, commonly known as 18/10 stainless, is often used in cutlery and high-quality cookware. 18/0 is also available.
Superaustenitic stainless steels, such as alloy AL-6XN and 254SMO, exhibit great resistance to chloride pitting and crevice corrosion because of high molybdenum content (>6%) and nitrogen additions, and the higher nickel content ensures better resistance to stress-corrosion cracking versus the 300 series. The higher alloy content of superaustenitic steels makes them more expensive. Other steels can offer similar performance at lower cost and are preferred in certain applications,for example ASTM A387 is used in pressure vessels but is a low-alloy carbon steel with a chromium content of 0.5% to 9%.[24] Low-carbon versions, for example 316L or 304L, are used to avoid corrosion problems caused by welding. Grade 316LVM is preferred where biocompatibility is required (such as body implants and piercings). The "L" means that the carbon content of the alloy is below 0.03%, which reduces the sensitization effect (precipitation of chromium carbides at grain boundaries) caused by the high temperatures involved in welding.Ferritic stainless steels generally have better engineering properties than austenitic grades, but have reduced corrosion resistance, because of the lower chromium and nickel content. They are also usually less expensive. They contain between 10.5% and 27% chromium and very little nickel, if any, but some types can contain lead. Most compositions include molybdenum; some, aluminium or titanium.Common ferritic grades include 18Cr-2Mo, 26Cr-1Mo, 29Cr-4Mo, and 29Cr-4Mo-2Ni. These alloys can be degraded by the presence of \sigma chromium, an intermetallic phase which can precipitate upon welding.
Swiss Army knives are made of martensitic stainless steel.Martensitic stainless steels are not as corrosion-resistant as the other two classes but are extremely strong and tough, as well as highly machinable, and can be hardened by heat treatment. Martensitic stainless steel contains chromium (12–14%), molybdenum (0.2–1%), nickel (less than 2%), and carbon (about 0.1–1%) (giving it more hardness but making the material a bit more brittle). It is quenched and magnetic.
Precipitation-hardening martensitic stainless steels have corrosion resistance comparable to austenitic varieties, but can be precipitation hardened to even higher strengths than the other martensitic grades. The most common, 17-4PH, uses about 17% chromium and 4% nickel.
Duplex stainless steels have a mixed microstructure of austenite and ferrite, the aim usually being to produce a 50/50 mix, although in commercial alloys the ratio may be 40/60. Duplex stainless steels have roughly twice the strength compared to austenitic stainless steels and also improved resistance to localized corrosion,particularly pitting, crevice corrosion and stress corrosion cracking. They are characterized by high chromium (19–32%) and molybdenum (up to 5%) and lower nickel contents than austenitic stainless steels.
The properties of duplex stainless steels are achieved with an overall lower alloy content than similar-performing super-austenitic grades, making their use cost-effective for many applications. Duplex grades are characterized into groups based on their alloy content and corrosion resistance. Lean duplex refers to grades such as UNS S32101 (LDX 2101), S32304, and S32003.
Standard duplex is 22% chromium with UNS S31803/S32205 known as 2205 being the most widely used.
Super duplex is by definition a duplex stainless steel with a Pitting Resistance Equivalent Number (PREN) > 40, where PREN = %Cr + 3.3x(%Mo + 0.5x%W) + 16x%N. Usually super duplex grades have 25% chromium or more and some common examples are S32760 (Zeron 100 via Rolled Alloys), S32750 (2507) and S32550 (Ferralium),.
Hyper duplex refers to duplex grades with a PRE > 48 and at the moment only UNS S32707 and S33207 are available on the market.

 
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